Back/Chemistry: Atoms First 2e
Section 20.418 Key Terms

Transmutation and Nuclear Energy

Learning Objectives
  • Write transmutation reactions and describe particle accelerators
  • Explain fission, fusion, chain reactions, and criticality
  • Describe nuclear reactor components and fusion confinement

Core Concepts & Principles

Nuclear Transmutation

Nuclear transmutation changes one nuclide into another, either through decay or an induced transmutation reaction. Bombarding a target with neutrons or other nuclei can change its proton and neutron counts. Charged projectiles must overcome electrostatic repulsion; particle accelerators use electric fields to accelerate them and magnetic fields to guide or focus their paths. Neutrons have no charge and are not accelerated this way.

Transuranium elements have Z>92Z>92. Most are produced artificially through particle bombardment or neutron capture followed by decay; traces of some, including plutonium, also occur naturally.

Fission and Chain Reactions

Fission splits a heavy nucleus into lighter fragments, usually releasing neutrons and a large amount of energy. One possible uranium-235 fission pathway is:

92235U+01n→56141Ba+3692Kr+3,01n^{235}_{92}\text{U} + ^1_0\text{n}\rightarrow ^{141}_{56}\text{Ba}+^{92}_{36}\text{Kr}+3,^1_0\text{n}

Fission can produce different fragment pairs. Released neutrons can trigger more fissions, forming a chain reaction. Fissionable means capable of fission; fissile more specifically includes material that fissions with slow neutrons, such as U-235. U-238 requires fast neutrons for fission.

  • Subcritical mass: Too few effective fission neutrons reach other nuclei; the chain reaction dies out.
  • Critical mass: Enough material, under specified conditions, to maintain a steady chain reaction: on average, each fission causes one more.
  • Supercritical mass: On average, each fission causes more than one further fission, so the rate grows.

Criticality depends on isotope composition, geometry, neutron leakage, and surrounding materials as well as mass. Joining subcritical pieces can make a system supercritical; uncontrolled rapid energy release is the basis of fission weapons.

Nuclear Fission Reactors

A nuclear reactor sustains a controlled chain reaction. Its main components are:

  • Nuclear fuel: Fissile material, often uranium enriched in U-235, arranged in fuel rods.
  • Nuclear moderator: Water, heavy water, or graphite slows neutrons so they can cause fission efficiently.
  • Control rods: Neutron absorbers such as boron or cadmium. Lowering rods reduces the reaction rate; raising them increases it.
  • Reactor coolant: Carries heat away from the core. Heat produces steam, directly or through a heat exchanger; steam drives a turbine and generator.
  • Containment system and shielding: Vessels, steel, and concrete contain pressure and radioactive material and reduce radiation exposure.

Spent fuel remains radioactive and needs cooling, shielding, and long-term management. Loss of cooling or containment can cause severe accidents, as illustrated by Three Mile Island, Chernobyl, and Fukushima.

Fusion

Fusion combines light nuclei into heavier ones. Suitable reactions release energy because the products are more tightly bound. For example:

12H+13H→24He+01n+17.6 MeV^2_1\text{H}+^3_1\text{H}\rightarrow ^4_2\text{He}+^1_0\text{n}+17.6\text{ MeV}

Fusion powers stars. Positively charged nuclei repel one another, so very high temperatures are needed to help overcome this Coulomb barrier. A fusion reactor must confine hot plasma long enough for useful reactions. Research approaches include magnetic confinement (tokamaks) and inertial confinement (intense laser pulses). Maintaining confinement and producing useful net energy are major challenges.

Energy Comes from a Mass Difference

In energy-releasing fission or fusion, products have less total mass than reactants. That difference appears as energy; nuclear energy changes are far larger than typical chemical energy changes.

Problem-Solving Routines & Methods

Nuclear Reaction Energy
Ereleased=(mreactants−mproducts)c2E_{\text{released}} = (m_{\text{reactants}}-m_{\text{products}})c^2

Use consistent masses for all particles, convert the mass difference to kilograms, and use c in m/s to obtain joules.

Balancing an Induced Nuclear Reaction
  1. 1
    Include the target nucleus and the incoming particle as reactants.
  2. 2
    Conserve the sum of mass numbers A and the sum of signed charge numbers Z separately.
  3. 3
    Identify any missing nucleus from Z, or a missing emitted particle from its A and Z.
  4. 4
    Check both sums before using the equation to calculate a mass or energy difference.

Practice & Concept Checks

Concept Check
Find the missing product: plutonium-239 plus an alpha particle produces one neutron and which nuclide?
Concept Check
What is the difference between a moderator and a control rod?
Concept Check
Why does fusion require extreme conditions?

Key Terms & Vocabulary

chain reactionFission and Chain Reactions
repeated fission caused when the neutrons released in fission bombard other atoms
containment systemNuclear Reactors
(also, shield) a three-part structure of materials that protects the exterior of a nuclear fission reactor and operating personnel from the high temperatures, pressures, and radiation levels inside the reactor
control rodNuclear Reactors
material inserted into the fuel assembly that absorbs neutrons and can be raised or lowered to adjust the rate of a fission reaction
critical massFission and Chain Reactions
amount of fissionable material that will support a self-sustaining (nuclear fission) chain reaction
fissile (or fissionable)Fission and Chain Reactions
when a material is capable of sustaining a nuclear fission reaction
Example: More precisely, fissile material can fission with slow neutrons. Fissionable is broader and includes nuclides that require fast neutrons.
fissionFission and Chain Reactions
splitting of a heavier nucleus into two or more lighter nuclei, usually accompanied by the conversion of mass into large amounts of energy
fusionFusion
combination of very light nuclei into heavier nuclei, accompanied by the conversion of mass into large amounts of energy
fusion reactorFusion
nuclear reactor in which fusion reactions of light nuclei are controlled
nuclear fuelNuclear Reactors
fissionable isotope present in sufficient quantities to provide a self-sustaining chain reaction in a nuclear reactor
nuclear moderatorNuclear Reactors
substance that slows neutrons to a speed low enough to cause fission
nuclear reactorNuclear Reactors
environment that produces energy via nuclear fission in which the chain reaction is controlled and sustained without explosion
nuclear transmutationNuclear Transmutation
conversion of one nuclide into another nuclide
particle acceleratorNuclear Transmutation
device that uses electric and magnetic fields to increase the kinetic energy of nuclei used in transmutation reactions
reactor coolantNuclear Reactors
assembly used to carry the heat produced by fission in a reactor to an external boiler and turbine where it is transformed into electricity
subcritical massFission and Chain Reactions
amount of fissionable material that cannot sustain a chain reaction; less than a critical mass
supercritical massFission and Chain Reactions
amount of material in which there is an increasing rate of fission
transmutation reactionNuclear Transmutation
bombardment of one type of nuclei with other nuclei or neutrons
transuranium elementNuclear Transmutation
element with an atomic number greater than 92; these elements do not occur in nature
Example: Most are made artificially, but traces of some transuranium elements occur naturally; the source's statement is a generalization.